Product ID:MGI 24875, PROPANE, CARBON MONOXIDE, AND (SUPDAT)
MSDS Date:12/30/1992
FSC:6830
NIIN:00N009378
MSDS Number: CDZJK

MG INDUSTRIES

3 GREAT VALLEY PARKWAY
MALVERN, PA 19355
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 215-695-7400

Cage: 08772

MG INDUSTRIES

MALVERN, PA 19355-1424 US

Telephone: 610-695-7400 / 610-695-7449

Cage: 08772

INSOMNIA, & PERSONALITY CHANGES, LARGELY DEPRESS AND

RTECS: 9999999ZZ

HYPER/HYPOVENTILATION, RESP ACIDOSIS, DEATH FROM

RTECS: 9999999ZZ

MAY BE ONLY SYMPS PRECEDING COLLAPSE.

RTECS: 9999999ZZ

DYSPNEA ON EXERTION, DECR MANUAL DEXTERITY, IMPAIRED

RTECS: 9999999ZZ

INSTABILITY, DIZZ, FATG, DROW, CONFUSION, NAUS,

RTECS: 9999999ZZ

PAIN, INCOORDINATION, HALLUCINATIONS, LETHARGY.

RTECS: 9999999ZZ

RESPIRATORY, BLOOD PRESSURE, AND PULSE, DEEPENING

RTECS: 9999999ZZ

SKIN DISCOLORATION, CYANOSIS AND PALLOR, INCREASED

RTECS: 9999999ZZ

HYPERREFLEXIA, ACHING, HEMMORHAGE, VENOUS

RTECS: 9999999ZZ

CARDIOVASCULAR AND CENTRAL

RTECS: 9999999ZZ

INFORMATION CONTACT NEHC .

RTECS: 9999999ZZ

NITROGEN

CAS: 7727-37-9

RTECS: QW9700000

Fraction By Weight: 80-95%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 4-12%

OSHA PEL 5000 PPM

ACGIH TLV: 5000 PPM/30000 STEL

CARBON MONOXIDE

CAS: 630-08-0

RTECS: FG3500000

Fraction By Weight: 4-12%

OSHA PEL 50 PPM

ACGIH TLV: 25 PPM

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

FOR 1/2 MILE IN ALL DIRECTIONS IF TANK, RAIL

RTECS: 9999999ZZ

INDICATED. COOL CYLS W/FLOODING AMTS OF WATER FROM AS

RTECS: 9999999ZZ

USE WATER SPRAY TO ABSORB VAPS. AVOID BRTHG VAPS.

RTECS: 9999999ZZ

TRACHYCARDIA & ARRHY, HYPOCALCEMIA

RTECS: 9999999ZZ

OF BLIND SPOTS, PHOTOPHOBIA, LOSS OF CONVERGENCE &

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CARBON MONOXIDE APPEARS ON NAVY
LISTING OF OCCUP CHEM REPROD HAZS. SEEK CONSULTATION FROM APPROP
HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG &
EXPOS INFO . ACUTE:NITROGEN:INH AL:DISSOLVES IN FAT-CONTAINING
BRAIN CELLS, & ACT AS ANESTH, CAUSING NARCOS. DECOMPRESSION
SICKNESS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CARBON DIOXIDE:VERY VOLAT. ACIDIC
TASTE, DYSPNEA, HDCH, VERTIGO, NAUS, LABORED BRTHG, WEAK, DROW,
MENTAL CONFUSN & INCR IN BLOOD PRESS, PULSE, & RESP RATE, VISUAL
DISTURB, TINNITUS, TREMORS, PROFUSE PERSPIRATION, RESTLESSNESS,
PARESTHESIAS, GENERAL FEELING OF DISCOMFORT, LOSS OF CONSCIOUSNESS
& COMA, (ING 8)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) .
EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR AT LEAST 15 MINS, SEEK
ASSISTANC E FROM MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL
MD . FOR MORE SPECIFIC INFORMATION ON FIRST AID CONTACT NEHC .

Extinguishing Media:DRY CHEMICAL/CARBON DIOXIDE. LARGER FIRES:USE WATER
SPRAY, FOG OR REGULAR FOAM.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNR FROM FIRE IF CAN BE DONE W/OUT RISK. APPLY COOLING WATER TO
SIDES OF CNTNRS THAT ARE EXPOS TO (SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME. CYLINDER MAY EXPLODE IN HEAT OF FIRE.

Spill Release Procedures:STOP LEAK IF CAN BE DONE W/OUT RISK. KEEP
UNNECESSARY PEOPLE AWAY; ISOLATE HAZARD AREA AND DENY ENTRY. STAY
UPWIND; KEEP OUT OF LOW AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE I/A/W 29 CFR 1910.101. STORE
AWAY FROM INCOMPATIBLE SUBSTANCES. DO NOT PERMIT PHYSICAL
DMG/OVERHEATING OF CONTAINERS.
Other Precautions:CONTENTS ARE UNDER PRESSURE; CONTAINERS MAY VIOLENTLY
RUPTURE AND TRAVEL CONSIDERABLE DISTANCE.

Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . FOR MORE SPECIFIC INFORMATION ON RESPIRATORS
CONTACT NEHC .
Ventilation:PROVIDE LOC EXHAUST/PROCESS ENCLOSURE VENT TO MEET EXPOS
LIMITS. VENT EQUIPMENT MUST BE EXPLOSION PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . AVOID
RPTD/PRLNGD CONTACT WITH SUBSTANCE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE NAME/PART NO:CARBON DIOXIDE IN NITROGEN. FIRE FIGHT
PROC:FLAMES UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF
TANKS. WITHDRAW IMMED IN CASE OF RISING SOUND FROM VENTING SFTY
DEVICE/AN Y DISCOLORATION OF TANK DUE TO FIRE. SOME OF THESE MATLS,
IF SPILLED, MAY EVAP LEAVING FLAMM RESIDUE. ISOLATE (ING 5)

Spec Gravity:>1.0
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:ODORLESS, COLORLESS GAS.

Stability Indicator/Materials to Avoid:YES
MAGNESIUM, BARIUM PEROXIDE, BROMINE TRIFLUORIDE, CHLORINE, CHLORINE
DIOXIDE. CONT NEHC FOR MORE SPECIFIC INFO .
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
TOXIC AND/OR HAZARDOUS GASES.

Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE,
CONTACT DISTRICT DIRECTOR OF ENVIRONMENTAL PROTECTION AGENCY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.